Alkali Ion Mobility in Mixed Cation Glasses (Part 1)
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چکیده
منابع مشابه
Optical and Thermal Properties of Mixed Alkali Phosphate Based Glasses
Glassy samples with a composition of 40P2O5–30V2O5–(30-x)Li2O– xK2O, 0<x<30 (mol %) were prepared by the conventional melt quenching technique in two forms of bulk and blown film. X-ray diffraction patterns corroborated the amorphous feature of the samples. Density of samples was investigated by using Archimedes principle. Based on absorption and reflection spectra, indirect a...
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In this work, mixed alkali metaphosphate glasses based on K-Na, Rb-Na, Rb-Li, Cs-Na and Cs-Li combinations were studied by differential scanning calorimetry (DSC), complex impedance spectroscopy, and Raman spectroscopy. DSC analyses show that both the glass transition (Tg) and melting temperatures (Tm) exhibit a clear mixed-ion effect. The ionic conductivity shows a strong mixed-ion effect and ...
متن کاملStructural Investigation, Physical and Optical Properties of Mixed Alkali Bismuth Borate Glasses
Lead free, eco-friendly bismuth borate glasses doped with alkali oxides of composition xLi2O+(30-x)Na2O+55B2O3+15Bi2O3 (x = 5,10,15,20,25) were prepared by melt quenching technique. Amorphous nature of glasses was confirmed by X-ray diffraction. Density measurements were carried out at room temperature by standard principle of Archimedes with Xylene as an immersion liquid. The non-linear ...
متن کاملModifier Interaction and Mixed-Alkali Effect in Bond Constraint Theory Applied to Ternary Alkali Metaphosphate Glasses
Introducing an interaction parameter γ, we implement modifier interaction and the mixed-alkali effect into bond constraint theory and apply this extension for simplistic property prediction on ternary phosphate glasses. The severity of the mixed-alkali effect results from the interplay of two simultaneous contributions: bond constraints on the modifier species soften and stiffen with decreasing...
متن کاملCation mass dependence of the nearly constant dielectric loss in alkali triborate glasses.
Electrical ac conductivity measurements on alkali triborate glasses ( M2O x 3B2O3, M = Li, Na, K, and Rb) were performed at temperatures down to 8 K and frequencies up to 1 GHz. All samples show a nearly constant dielectric loss (NCL), at the limit of high frequencies and/or low temperatures. The magnitude of the NCL is found to decrease as m(-1/3) with increasing alkali ion mass m. This quanti...
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ژورنال
عنوان ژورنال: Journal of the Ceramic Association, Japan
سال: 1986
ISSN: 1884-2127,0009-0255
DOI: 10.2109/jcersj1950.94.1091_677